Melt flow properties and morphology of polypropylene composites filled with microencapsulated red phosphorus. (February 2015)

• Record Type: Journal Article
• Authors: Liang, Ji-Zhao; Feng, Jin-Qing; Tsui, Chi-Pong; Tang, Chak-Yin
• Is Part Of: Journal of thermoplastic composite materials. Volume 28:Number 2(2015:Mar.)
• Page Start: 275
• Page End: 286
• Publication Date: 2015-02
• Subjects: Polymer–matrix composites -- rheological properties -- extrusion -- resin flow; Thermoplastic composites -- Periodicals; 668.423
• DOI: 10.1177/0892705713484741
• Languages: English
• ISSNs: 0892-7057

Abstract

Microencapsulated red phosphorus (MRP)-filled polypropylene (PP) composites were prepared using a twin-screw extruder. The effects of load and temperature as well as the dispersion or distribution of the filler particles in the matrix on the melt volume flow rate (MVR) and melt density ( ρ m ) of the PP/MRP composites were investigated using a melt flow indexer and a scanning electron microscope. The temperatures and loads were varied from 180 to 205°C and from 2.16 to 12.5 kg, respectively. The results showed that the MVR of the composites increased nonlinearly with increase in temperature and load. The sensitivity of MVR of the composite melts to temperature was significant. The MVR of the composites also decreased slightly with an increase in the MRP weight fraction. However, the values of ρ m of the composites varied slightly with increase in load, temperature, and MRP weight fraction. The findings can provide useful information for optimum processing of these composites.