A PPy/Cu2O molecularly imprinted composite film-based visible light-responsive photoelectrochemical sensor for microcystin-LR. Issue 15 (20th March 2018)

• Record Type: Journal Article
• Authors: Chen, Junli; Gao, Pan; Wang, Hai; Han, Lifeng; Zhang, Yonghui; Wang, Peiyuan; Jia, Nengqin
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 15(2018)
• Page Start: 3937
• Page End: 3944
• Publication Date: 2018-03-20
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7tc05743a
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : In this study, a visible light-responsive photoelectrochemical (PEC) sensor based on a PPy/Cu2 O molecularly imprinted composite film for microcystin-LR (MC-LR) has been fabricated. Abstract : In this study, a visible light-responsive photoelectrochemical (PEC) sensor based on a PPy/Cu2 O molecularly imprinted composite film for microcystin-LR (MC-LR) has been fabricated. Uniform Cu2 O nanoparticles were electrodeposited on a pretreated indium-doped tin oxide-coated glass (ITO) by carefully controlling the deposition process and used as a photocatalyst to produce photocurrent under visible light. Subsequently, molecularly imprinted polypyrrole (PPy) was modified on the surface of the Cu2 O/ITO electrode by an electropolymerization process, which created a certain amount of special recognition sites to enhance the selectivity of the electrode to MC-LR. PEC molecular imprinting sensors were used to rapidly analyze MC-LR concentration by determining changes in photocurrent density. The results showed that the change of photocurrent density was linearly proportional to the logarithm of the MC-LR concentration over the ranges from 1.0 ng L −1 to 100 ng L −1 and from 100 ng L −1 to 10.0 μg L −1 with a low detection limit of 0.23 ng L −1 (S/N = 3). Moreover, the PEC sensors exhibited specific selectivity to MC-LR when exposed to certain concentrations of interfering solutions. The constructed PEC sensors demonstrated good applicability in local water systems; this suggested that this promising application of integrating PEC and molecular imprinting technology could be applied to detect other contaminants of emerging concern.