Modeling of local maskless electrochemical deposition of metal microcolumns. (29th June 2018)

• Record Type: Journal Article
• Authors: Volgin, V.M.; Kabanova, T.B.; Davydov, A.D.
• Is Part Of: Chemical engineering science. Volume 183(2018)
• Page Start: 123
• Page End: 135
• Publication Date: 2018-06-29
• Subjects: Localized electrodeposition -- Numerical simulation -- Morphology of deposit -- Edge effect; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; Chemical engineering; Periodicals; Electronic journals; 660
• DOI: 10.1016/j.ces.2018.03.019
• Languages: English
• ISSNs: 0009-2509

Abstract

Graphical abstract: Highlights: Theoretical analysis of current distribution in electrodeposition of microstructures. Analytical solution of problem of local metal electrodeposition. Mathematical model and numerical solution of problem of local electrodeposition. Edge effect in local electrodeposition of microstructures. Relations between electrodeposition parameters and microstructure shape and dimensions. Abstract: The work deals with the problem of fabricating new materials for modern devices of microelectromechanics, microelectronics, biomimetics, etc. using the local electrodeposition of metals. The mathematical model is developed for the formation of 3D microstructures (microcolumns) by the local electrochemical deposition of metal using a moving disk microanode. The numerical solution of the mathematical problem is performed using the finite element method on the irregular grid. The grid is deformed and adaptively remeshed during modeling of deposit growth. Evolution of deposit surface is calculated for various exchange current densities, transfer coefficients, interelectrode distances and various dependences of the current efficiency on the current density. The results of modeling allow one to determine the relationships between the parameters of electrodeposition and the shape and dimensions of formed microstructures. These data can be used to predict the results of local electrodeposition of metal and to optimize the operation conditions.