Lattice tilt and strain mapped by X‐ray scanning nanodiffraction in compositionally graded SiGe/Si microcrystals. Issue 2 (1st March 2018)

• Record Type: Journal Article
• Authors: Meduňa, Mojmír; Isa, Fabio; Jung, Arik; Marzegalli, Anna; Albani, Marco; Isella, Giovanni; Zweiacker, Kai; Miglio, Leo; von Känel, Hans
• Is Part Of: Journal of applied crystallography. Volume 51:Issue 2(2018)
• Page Start: 368
• Page End: 385
• Publication Date: 2018-03-01
• Subjects: scanning X‐ray nanodiffraction -- lattice bending -- graded SiGe microcrystals -- strain relaxation; Crystallography -- Periodicals; 548.05
• DOI: 10.1107/S1600576718001450
• Languages: English
• ISSNs: 0021-8898

Abstract

Abstract : The high‐resolution three‐dimensional distribution of lattice tilt and shape in Ge compositionally graded SiGe microcrystals is reconstructed using scanning X‐ray nanodiffraction. The obtained intensity reciprocal‐space maps and tilt real‐space maps prove the start of defect formation for various crystal sizes and Ge grading rates, in excellent agreement with previous observations using transmission electron microscopy and defect etching. Abstract : The scanning X‐ray nanodiffraction technique is used to reconstruct the three‐dimensional distribution of lattice strain and Ge concentration in compositionally graded Si1− x Ge x microcrystals grown epitaxially on Si pillars. The reconstructed crystal shape qualitatively agrees with scanning electron micrographs and the calculated three‐dimensional distribution of lattice tilt quantitatively matches finite‐element method simulations. The grading of the Ge content obtained from reciprocal‐space maps corresponds to the nominal grading of the epitaxial growth recipe. The X‐ray measurements confirm strain calculations, according to which the lattice curvature of the microcrystals is dominated by the misfit strain, while the thermal strain contributes negligibly. The nanodiffraction experiments also indicate that the strain in narrow microcrystals on 2 × 2 µm Si pillars is relaxed purely elastically, while in wider microcrystals on 5 × 5 µm Si pillars, plastic relaxation by means of dislocations sets in. This confirms previous work on these structures using transmission electron microscopy and defect etching.