Kinetic stabilization of a Ni(ii) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure. Issue 20 (14th February 2018)

• Record Type: Journal Article
• Authors: Hosomi, Takuro; Harada, Ryosuke; Masai, Hiroshi; Fujihara, Tetsuaki; Tsuji, Yasushi; Terao, Jun
• Is Part Of: Chemical communications. Volume 54:Issue 20(2018)
• Page Start: 2487
• Page End: 2490
• Publication Date: 2018-02-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc00351c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : We describe herein the synthesis of a Ni(ii ) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Abstract : We describe herein the synthesis of a Ni(ii ) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation. Under cyclic voltammetry conditions, the complex showed a stable and reversible redox behavior in contrast to a non-insulated reference complex, clearly demonstrating the effectiveness of the rotaxane-type insulation as a new method of kinetic metal complex stabilization.