An electrophilic reagent for the synthesis of OCHFMe-containing molecules. Issue 20 (19th February 2018)

• Record Type: Journal Article
• Authors: Carbonnel, Elodie; Pannecoucke, Xavier; Besset, Tatiana; Jubault, Philippe; Poisson, Thomas
• Is Part Of: Chemical communications. Volume 54:Issue 20(2018)
• Page Start: 2491
• Page End: 2493
• Publication Date: 2018-02-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc00921j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Herein the synthesis of a novel and bench stable electrophilic reagent to construct the OCFHMe motif from O -nucleophiles has been described. Abstract : Herein the synthesis of a novel and bench stable electrophilic reagent to construct the OCFHMe motif from O -nucleophiles has been described. This sulfonium salt, readily obtained in 5 steps, reacted with various phenols and alcohols. The resulting products, including complex molecules, were obtained in good yields. This reagent was also used for the functionalization of thiol derivatives.