Interdigitated back-contacted crystalline silicon solar cells with low-temperature dopant-free selective contacts. Issue 9 (9th February 2018)

• Record Type: Journal Article
• Authors: Masmitjà, G.; Ortega, P.; Puigdollers, J.; Gerling, L. G.; Martín, I.; Voz, C.; Alcubilla, R.
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 9(2018)
• Page Start: 3977
• Page End: 3985
• Publication Date: 2018-02-09
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7ta11308k
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A new Al2 O3 /TiO2 /Mg electron-contact scheme together with a V2 O x -based hole-contact is applied to cold-IBC solar cells achieving efficiencies beyond 19%. Abstract : In the field of crystalline silicon solar cells, great efforts are being devoted to the development of selective contacts in search of a fully low-temperature and dopant-free fabrication process compatible with high photovoltaic conversion efficiencies. For high-efficiency devices, selective contacts have to simultaneously combine high conductivity with excellent passivating properties. With this objective, a thin passivating extra layer of a-Si:H or SiO2 is usually introduced between the conducting layer and the silicon substrate. In this work, we present an interdigitated back-contacted (IBC) silicon based solar cell that avoids the use of either thermal SiO2 or a-Si:H interlayers achieving a dopant-free, ITO-free and very low thermal budget fabrication process. In this work, we propose a new electron transport layer using ultrathin Al2 O3 /TiO2 stacks deposited by atomic layer deposition at 100 °C covered with a thermally evaporated Mg capping film. A specific contact resistance of 2.5 mΩ cm 2 has been measured together with surface recombination velocities below 40 cm s −1 . This electron-selective contact is combined with a thermally evaporated V2 O x -based hole selective contact to form the rear scheme of an IBC structure with a 3 × 3 cm 2 active area as a proof-of-concept resulting in efficiencies beyond 19%. This approach sheds light on potential technological simplification and cost reduction in crystalline silicon solar cells.