Crystal structure and mechanical properties of spark plasma sintered Cu2Se: An efficient photovoltaic and thermoelectric material. (April 2015)

• Record Type: Journal Article
• Authors: Tyagi, Kriti; Gahtori, Bhasker; Bathula, Sivaiah; Jayasimhadri, M.; Sharma, Sakshi; Singh, Niraj Kumar; Haranath, D.; Srivastava, A.K.; Dhar, Ajay
• Is Part Of: Solid state communications. Volume 207(2015)
• Page Start: 21
• Page End: 25
• Publication Date: 2015-04
• Subjects: A. Semiconductor -- C. Scanning and transmission electron microscopy -- D. Mechanical properties -- D. Phase transitions; Solid state chemistry -- Periodicals; Solid state physics -- Periodicals; Chimie de l'état solide -- Périodiques; Physique de l'état solide -- Périodiques; 530.41
• DOI: 10.1016/j.ssc.2015.02.004
• Languages: English
• ISSNs: 0038-1098

Abstract

Abstract: Copper selenide (Cu2 Se) based materials are currently being investigated globally for efficient photovoltaic and thermoelectric (TE) device applications. Despite having enormous device potential its crystal structure and mechanical properties are still not fully explored owing to its complex behavior. Stereographic projection is one of such useful tools to estimate the crystallography of the material conclusively. In the current study, the crystal structure of α and β -phases of Cu2 Se was determined by its stereographic projections in reciprocal space. Further, mechanical properties of Cu2 Se are highly important to avoid catastrophic failure and ensure longevity of the TE devices made out of these materials. Cu2 Se exhibited the compressive strength of ~45 MPa with ~3% of plastic strain and a fracture toughness value of ~2±0.02 MPa√m, the latter being significantly higher than that of the other known TE materials. Finally, thermal shock resistance, which is one of the crucial parameters for the stability and longevity of the device applications, was calculated to be ~281±12 W m −1 . Superior mechanical properties coupled with highly reported thermoelectric behavior makes Cu2 Se as a potential candidate for green energy generation. Highlights: Crystal structure determination by stereographic projections for Cu2 Se. Superior mechanical properties coupled with high thermoelectric performance. Improved fracture toughness, compressive strength and thermal shock resistance.