Formation of structural defects and strain in electrodegraded Fe‐doped SrTiO3 crystals due to oxygen vacancy migration. Issue 6 (6th January 2018)

• Record Type: Journal Article
• Authors: Ascienzo, David; Kurt, Onur; Greenbaum, Steve; Bayer, Thorsten J. M.; Maier, Russell A.; Randall, Clive A.; Ren, Yuhang
• Is Part Of: Journal of the American Ceramic Society. Volume 101:Issue 6(2018)
• Page Start: 2545
• Page End: 2561
• Publication Date: 2018-01-06
• Subjects: electroceramic -- oxygen vacancy -- perovskite -- raman spectroscopy -- second harmonic generation; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.15407
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: We report on our investigation of structural defect and strain formation in electrodegraded reduced and oxidized, Fe ‐doped SrTiO 3 (Fe:STO) single crystals using optical second harmonic generation (SHG) and confocal Raman spectroscopy. SHG and Raman spectra reveal structural and electrochemical inhomogeneity resulting from the formation of Fe 4+ /oxygen ion and Fe 3+ /oxygen vacancy aggregation sites along the degraded anode and cathode interfaces, respectively. We show that mixed Fe 3+ /Fe 4+ states and structural strain gradients are generated across the color fronts. These results, as well as oxygen sublattice differences between the anodic and cathodic bulk, present the color front as an interface between two dominant oxygen bonding distortions. The strain near the color front shows a strong dependence on oxygen vacancy concentration and diffusion within the crystals. Our characterization of structural and electrochemical changes due to electric field‐induced strain and oxygen vacancy migration advances knowledge of electrodegradation in perovskite‐based titanate single crystals.