Controlling the crystallinity and crystalline orientation of "shuttlecock" naphthalocyanine films for near-infrared optoelectronic applications. Issue 8 (6th February 2018)

• Record Type: Journal Article
• Authors: Dalgleish, Simon; Reissig, Louisa; Shuku, Yoshiaki; Gourlaouen, Christophe; Vela, Sergi; Awaga, Kunio
• Is Part Of: Journal of materials chemistry. Volume 6:Issue 8(2018)
• Page Start: 1959
• Page End: 1970
• Publication Date: 2018-02-06
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7tc05521h
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Thin films of Sn(ii ) 2, 3-naphthalocyanine display rich polymorphism and tunable crystallinity with striking effects on their optical and optoelectronic properties. Abstract : The thin film properties of tin(ii ) 2, 3-naphthalocyanine (SnNPc) were interrogated and various strategies for controlling the crystallinity and crystalline orientation within the films were assessed. SnNPc is shown to crystallize in the space group P 21 / c ( Z = 4), where the molecular arrangement consists of alternating layers of concave and convex overlap, induced by the out-of-plane Sn atoms, resulting in a 3D slipped-π-stack network structure analogous to that reported for Phase I of titanyl phthalocyanine. The thin films were studied by X-ray diffraction, atomic force microscopy and absorption spectroscopy and are highly sensitive not just to the conditions during growth, but also to substrate pre- and post-deposition treatment. While the films grown at room temperature were largely amorphous, the crystallinity was enhanced with substrate temperature, with the molecules orienting in a standing molecular geometry. A thin layer of 3, 4:9, 10-perlenetetracarboxylic dianhydride induces a lying molecular geometry of the same polymorph as that of the single crystal, while different polymorphs are accessible through solvent vapor annealing of amorphous films. Transient photocurrent measurements showed a dramatic improvement in photodetector device bandwidth for the lying molecular geometry, which was attributed to enhanced photoconductivity along the π-stacking axis, while solvent vapor annealing could be used to tune the photosensitivity across the near-infrared region.