Swelling properties of thermoresponsive/hydrophilic co-networks with functional crosslinked domain structures. Issue 13 (8th January 2018)

• Record Type: Journal Article
• Authors: Ida, Shohei; Kitanaka, Hironobu; Ishikawa, Tatsuya; Kanaoka, Shokyoku; Hirokawa, Yoshitsugu
• Is Part Of: Polymer chemistry. Volume 9:Issue 13(2018)
• Page Start: 1701
• Page End: 1709
• Publication Date: 2018-01-08
• Subjects: Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1039/c7py01793f
• Languages: English
• ISSNs: 1759-9954

Abstract

Abstract : We focused on the monomer/crosslinker sequence in a gel network and designed novel thermoresponsive/hydrophilic amphiphilic co-networks with crosslinked domain structures. Abstract : For the fine control of the thermoresponsive properties of polymer hydrogels, we focused on the monomer and crosslinker sequence in a network. In this paper, we designed novel thermoresponsive/hydrophilic polymer co-networks with functional crosslinked domain (CD) structures such as a thermoresponsive network with hydrophilic CDs (D CD N gel) and a hydrophilic network with thermoresponsive CDs (N CD D gel). The gel synthesis was based on post-polymerization crosslinking of triblock prepolymers with reactive sites in the outer blocks. The obtained gels showed larger, sharper, and more rapid volume transitions in response to temperature change as compared to the corresponding gel with a random monomer/crosslinker sequence as well as a randomly crosslinked polymer co-network with the same composition. In addition, significant differences were observed in the transition temperature and shrinking kinetics betweenD CD N andN CD D gels with the same composition and a similar network structure, and the swelling behavior was also controlled by the composition of the triblock prepolymers. These results indicated that the domain structure in the network could effectively function and the monomer/crosslinker sequence exerts a strong effect on the swelling behavior of the gels.