Laser cutting of lithium iron phosphate battery electrodes: Characterization of process efficiency and quality. (January 2015)

• Record Type: Journal Article
• Authors: Lutey, Adrian H.A.; Fortunato, Alessandro; Ascari, Alessandro; Carmignato, Simone; Leone, Claudio
• Is Part Of: Optics & laser technology. Volume 65(2015)
• Page Start: 164
• Page End: 174
• Publication Date: 2015-01
• Subjects: Laser cutting -- Battery electrodes -- LiFePO4; Optics -- Periodicals; Lasers -- Periodicals; Electronic journals; 621.366
• DOI: 10.1016/j.optlastec.2014.07.023
• Languages: English
• ISSNs: 0030-3992

Abstract

Abstract: Lithium iron phosphate battery electrodes are subject to continuous-wave and pulsed laser irradiation with laser specifications systematically varied over twelve discrete parameter groups. Analysis of the resulting cuts and incisions with an optical profiler and scanning electron microscope gives insight into the dominant physical phenomena influencing laser cutting efficiency and quality. Measured incision depths are found to be piece-wise functions of average laser power, with the metallic conductor layers dominating the process due to their high thermal conductivity and low optical absorptance relative to the active coating layers. Cutting efficiency improves with shorter laser pulses and use of 532 nm radiation in place of 1064 nm. Complete electrode penetration takes place at lowest average power with pulse fluence in the ranges 35–40 J/cm 2 and 100–110 J/cm 2 for the cathode and anode, respectively, with 1064 nm beam wavelength. Per-pulse ablation depths are derived for the active coating layers under all tested conditions, giving new insight into the ablation behavior of each individual material. Defect size and coating layer delamination width are both found to be linked to cutting efficiency, with highest quality achieved for a given wavelength when overall cutting efficiency is optimized. Ideal parameters are found to be those maximizing the ablation efficiency of the metallic layers, as residual heat deposition in the films is minimized. Abstract : Highlights: Lithium iron phosphate battery electrodes are exposed to CW and pulsed laser radiation. Incision depths are obtained for 12 laser parameter groups at 100 mm/s, 500 mm/s and 1 m/s. Cutting efficiency increases with shorter pulses, higher velocity and shorter wavelength. Per-pulse ablation rates derived for LiFePO4 highlight the negative impact of pulse overlap. Defect size and layer delamination decrease with increasing cutting efficiency.