Co(OH)2 Nanoparticle‐Encapsulating Conductive Nanowires Array: Room‐Temperature Electrochemical Preparation for High‐Performance Water Oxidation Electrocatalysis. Issue 9 (15th January 2018) - Wu, Dan
Abstract: It is highly desired but still remains challenging to design and develop a Co‐based nanoparticle‐encapsulated conductive nanoarray at room temperature for high‐performance water oxidation electrocatalysis. Here, it is reported that room‐temperature anodization of a Co(TCNQ)2 (TCNQ= tetracyanoquinodimethane) nanowire array on copper foam at alkaline pH leads to in situ electrochemcial oxidation of TCNQ − into water‐insoluable TCNQ nanoarray embedding Co(OH)2 nanoparticles. Such Co(OH)2 ‐TCNQ/CF shows superior catalytic activity for water oxidation and demands only a low overpotential of 276 mV to drive a geometrical current density of 25 mA cm −2 in 1.0m KOH. Notably, it also demonstrates strong long‐term electrochemical durability with its activity being retrained for at least 25 h, a high turnover frequency of 0.97 s −1 at an overpotential of 450 mV and 100% Faradic efficiency. This study provides an exciting new method for the rational design and development of a conductive TCNQ‐based nanoarray as an interesting 3D material for advanced electrochemical applications. Abstract : A Co(OH)2 nanoparticle‐encapsulating conductive tetracyanoquinodimethane (TCNQ) nanowire array on copper foam is prepared using an in situ electrochemical oxidation method to form a water‐insoluable conductive TCNQ nanoarray. This array effectively entraps Co(OH)2 nanoparticles at alkaline pH. Such Co(OH)2 ‐TCNQ/CF requires an overpotential as low as 276 mV to drive a geometrical current density of 25 mA cm −2 in 1.0 M KOH, with strong long‐term electrochemical durability.