Comprehensive Understanding of the Spatial Configurations of CeO2 in NiO for the Electrocatalytic Oxygen Evolution Reaction: Embedded or Surface‐Loaded. (17th January 2018)

• Record Type: Journal Article
• Authors: Gao, Wei; Xia, Zhaoming; Cao, Fangxian; Ho, Johnny C.; Jiang, Zheng; Qu, Yongquan
• Is Part Of: Advanced functional materials. Volume 28:Number 11(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-01-17
• Subjects: CeO2 -- electocatalysis -- NiO -- oxygen evolution -- spatial configurations; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201706056
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Introducing cerium (Ce) species into electrocatalysts has been recently developed as an effective approach to improve their oxygen evolution reaction (OER) performance. Importantly, the spatial distribution of Ce species in the hosts can determine the availability of Ce species either as additives or as co‐catalysts, which would dictate their different contributions to the enhanced electrocatalytic performance. Herein, the comprehensive investigations on two different catalyst configurations, namely CeO2 ‐embedded NiO (Ce‐NiO‐E) and CeO2 ‐surface‐loaded NiO (Ce‐NiO‐L), are performed to understand the effect of their specific spatial arrangements on OER characteristics. The Ce‐NiO‐E catalysts exhibit a smaller overpotential of 382 mV for 10 mA cm −2 and a lower Tafel slope of 118.7 mV dec −1, demonstrating the benefits of the embedded configuration for OER, as compared with those of Ce‐NiO‐L (426 mV and 131.6 mV dec −1 ) and pure NiO (467 mV and 140.7 mV dec −1 ), respectively. The improved OER property of Ce‐NiO‐E originates from embedding small‐sized CeO2 clusters into the host for the larger specific surface area, richer surface defects, higher oxygen adsorption capacity, and better optimized electronic structures of the surface active sites, as compared with Ce‐NiO‐L. Above findings provide a valuable guideline for and insight in designing catalysts with different spatial configurations for enhanced catalytic properties. Abstract : Spatial distribution of CeO2 species as additives in the NiO host can dictate different contributions to the enhanced electrocatalytic oxygen evolution performance. The comparative study on two different catalyst configurations showed the benefits of embedding small‐sized CeO2 clusters into NiO to modify the surface properties and structures and improve the activity as compared with CeO2 surface‐loaded NiO.