Sr‐Nd‐Hf Isotopic Analysis of <10 mg Dust Samples: Implications for Ice Core Dust Source Fingerprinting. (12th January 2018)

• Record Type: Journal Article
• Authors: Újvári, Gábor; Wegner, Wencke; Klötzli, Urs; Horschinegg, Monika; Hippler, Dorothee
• Is Part Of: Geochemistry, geophysics, geosystems. Volume 19:Number 1(2018)
• Page Start: 60
• Page End: 72
• Publication Date: 2018-01-12
• Subjects: dust -- provenance -- ice core -- Sr‐Nd‐Hf isotopes -- trace elements; Geochemistry -- Periodicals; Geophysics -- Periodicals; Earth sciences -- Periodicals; 550.5
• DOI: 10.1002/2017GC007136
• Languages: English
• ISSNs: 1525-2027

Abstract

Abstract: Combined Sr‐Nd‐Hf isotopic data of two reference materials (AGV‐1/BCR2) and 50, 10, and 5 mg aliquots of carbonate‐free fine grain (&lt;10 μm) separates of three loess samples (Central Europe/NUS, China/BEI, USA/JUD) are presented. Good agreement between measured and reference Sr‐Nd‐Hf isotopic compositions (ICs) demonstrate that robust isotopic ratios can be obtained from 5 to 10 mg size rock samples using the ion exchange/mass spectrometry techniques applied. While 87 Sr/ 86 Sr ratios of dust aluminosilicate fractions are affected by even small changes in pretreatments, Nd isotopic ratios are found to be insensitive to acid leaching, grain‐size or weathering effects. However, the Nd isotopic tracer is sometimes inconclusive in dust source fingerprinting (BEI and NUS both close to ɛNd(0) –10). Hafnium isotopic values (&lt;10 μm fractions) are homogenous for NUS, while highly variable for BEI. This heterogeneity and vertical arrays of Hf isotopic data suggest zircon depletion effects toward the clay fractions (&lt;2 μm). Monte Carlo simulations demonstrate that the Hf IC of the dust &lt;10 μm fraction is influenced by both the abundance of zircons present and maturity of crustal rocks supplying this heavy mineral, while the &lt;2 μm fraction is almost unaffected. Thus, ɛHf(0) variations in the clay fraction are largely controlled by the Hf IC of clays/heavy minerals having high Lu/Hf and radiogenic 176 Hf/ 177 Hf IC. Future work should be focused on Hf IC of both the &lt;10 and &lt;2 μm fractions of dust from potential source areas to gain more insight into the origin of last glacial dust in Greenland ice cores. Key Points: Combined Sr‐Nd‐Hf isotopic ratios were obtained from small size (5–10 mg) dust samples European/North American dusts have less radiogenic Hf isotopic signatures than those of SE Asian dust Modeling suggests that ɛHf(0) of the &lt;2 μm fraction of dust is negligibly affected by zircons and may distinguish between dust sources