Highly Substituted Cyclohexenes via Phosphine‐Catalyzed [4+2] Annulation of Electron‐deficient Dienes and Vinyl Ketones. Issue 4 (14th December 2017)

• Record Type: Journal Article
• Authors: Chen, Peng; Zhang, Junyou; Zhang, Junliang
• Is Part Of: Advanced synthesis & catalysis. Volume 360:Issue 4(2018)
• Page Start: 682
• Page End: 685
• Publication Date: 2017-12-14
• Subjects: [4+2] annulation -- electron-deficient diene -- Vinyl Ketone -- Phosphine catalyst -- Cyclohexene; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201701168
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: A highly efficient phosphine‐catalyzed [4+2] annulation of electron‐deficient diene and alkyl vinyl ketone was developed for the first time, which provides an easy access to functionalized cyclohexenes. This method has the advantages of mild reaction conditions, widely functional group tolerance, high yields and transition metal free. Abstract :