An efficient recycling process of glycolysis of PET in the presence of a sustainable nanocatalyst. Issue 21 (7th February 2018)

• Record Type: Journal Article
• Authors: Guo, Zengwei; Lindqvist, Karin; de la Motte, Hanna
• Is Part Of: Journal of applied polymer science. Volume 135:Issue 21(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-02-07
• Subjects: catalysts -- fibers -- nanoparticles -- nanowires -- nanocrystals -- polyesters -- recycling; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.46285
• Languages: English
• ISSNs: 0021-8995

Abstract

ABSTRACT: We demonstrate that the catalyst Perkalite F100 efficiently works as a nanocatalyst in the depolymerization of poly(ethylene terephthalate) (PET). After depolymerization of PET in the presence of ethylene glycol and the Perkalite nanocatalyst, the main product obtained was bis(2‐hydroxylethyl) terephthalate (BHET) with high purity, as confirmed by Fourier transform infrared spectroscopy and NMR. The BHET monomers could serve directly as starting materials in a further polymerization into PET with a virgin quality and contribute to a solution for the disposal of PET polymers. Compared with the direct glycolysis of PET, the addition of a predegradation step was shown to reduce the reaction time needed to reach the depolymerization equilibrium. The addition of the predegradation step also allowed lower reaction temperatures. Therefore, the strategy to include a predegradation step before depolymerization is suitable for increasing the efficiency of the glycolysis reaction of PET into BHET monomers. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2018, 135, 46285. Abstract :