Aerobic Photooxidative Synthesis of β‐Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base. Issue 4 (1st February 2018)

• Record Type: Journal Article
• Authors: Asano, Yuya; Nagasawa, Yoshitomo; Yamaguchi, Eiji; Itoh, Akichika
• Is Part Of: Chemistry, an Asian journal. Volume 13:Issue 4(2018)
• Page Start: 409
• Page End: 412
• Publication Date: 2018-02-01
• Subjects: acridinium catalyst -- alkenes -- hydroperoxide synthesis -- oxygen -- photocatalysis; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201701742
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: Transition‐metal‐free synthesis of β‐alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost‐effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system. Abstract : You can do it for free : Transition‐metal‐free synthesis of β‐alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost‐effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.