A Cryptand Metal–Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations. Issue 10 (20th January 2017)

• Record Type: Journal Article
• Authors: Sapchenko, Sergey A.; Demakov, Pavel A.; Samsonenko, Denis G.; Dybtsev, Danil N.; Schröder, Martin; Fedin, Vladimir P.
• Is Part Of: Chemistry. Volume 23:Issue 10(2017)
• Page Start: 2286
• Page End: 2289
• Publication Date: 2017-01-20
• Subjects: alkali metal recognition -- cryptands -- luminescent detectors -- metal–organic frameworks -- sensing; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201605895
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: The metal–organic framework (MOF) complex (H3 O)2 [Zn4 (ur)(Hfdc)2 (fdc)4 ] (1, ur=urotropine, H2 fdc=furan‐2, 5‐dicarboxylic acid) incorporates cryptand‐like cavities, which can be used to separate and detect Rb + and Cs + optically. This is the first example of the effective employment of a MOF material for optical detection of these cations. Abstract : Detector MOF : (H3 O)2 [Zn4 (ur)(Hfdc)2 (fdc)4 ] (1, ur=urotropine, H2 fdc=furan‐2, 5‐dicarboxylic acid) incorporates cryptand‐like cavities, which can be used to separate and detect Rb + and Cs + optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.