Estimation of the effect of catalyst physical characteristics on Fenton-like oxidation efficiency using adaptive neuro-fuzzy computing technique. (January 2015)

• Record Type: Journal Article
• Authors: Rahim Pouran, Shima; Abdul Aziz, A.R.; Wan Daud, Wan Mohd Ashri; Shamshirband, Shahaboddin
• Is Part Of: Measurement. Volume 59(2015:Jan.)
• Page Start: 314
• Page End: 328
• Publication Date: 2015-01
• Subjects: Adaptive neuro-fuzzy system (ANFIS) -- Adsorption capacity -- Central composite design -- Heterogeneous Fenton treatment; Weights and measures -- Periodicals; Measurement -- Periodicals; Measurement; Weights and measures; Periodicals; 530.8
• DOI: 10.1016/j.measurement.2014.09.060
• Languages: English
• ISSNs: 0263-2241

Abstract

Highlights: Catalyst size as one of the factors in catalytic performance. Response surface methodology (RSM). Adaptive neuro-fuzzy inference system (ANFIS) application. To quantify the effects of physical characteristics of magnetite. Fenton-like oxidation efficiency of methylene blue. Abstract: Catalyst size, which determines surface area, is one of the major factors in catalytic performance. In this study, response surface methodology (RSM) and an adaptive neuro-fuzzy inference system (ANFIS) were applied to quantify the effects of physical characteristics of magnetite on Fenton-like oxidation efficiency of methylene blue. For this purpose, two magnetite samples (M and N) were used and characterized by XRD, BET surface area, particle size analyzer and FE-SEM. Central composite design (CCD) was applied to design the experiments, develop regression models, optimize and evaluate the individual and interactive effects of five independent variables: H2 O2 and catalyst concentrations, pH, reaction time (numeric factors) and the type of catalyst (categorical factor). For each categorical factor, three quadratic models were developed regarding target responses: decolorization (YMB ), COD (YCOD ) and TOC (YTOC ) removal efficiencies (%). The quadratic models were estimated by CCD and ANFIS methodologies. ANFIS was implemented using Matlab/Simulink and the performances were investigated. ANFIS models performed better for catalyst N compared to catalyst M, for color, COD and TOC separately. On contrary, it performed better for catalyst M compared to catalyst N, for combinations of color, COD and TOC. The obtained RMSE and R 2 for the ANFIS networks show the effectiveness of catalyst N compared to catalyst M in Fenton oxidation process.