Enhancement of the oxygen desorption/absorption property of BaFe1−xInxO3−δ by In substitution for Fe site. Issue 4 (27th November 2017)

• Record Type: Journal Article
• Authors: Fujishiro, Fumito; Izaki, Minako; Hashimoto, Takuya
• Is Part Of: Journal of the American Ceramic Society. Volume 101:Issue 4(2018)
• Page Start: 1696
• Page End: 1703
• Publication Date: 2017-11-27
• Subjects: BaFe1−xInxO3−δ -- high‐temperature X‐ray diffraction -- oxygen desorption -- perovskite‐type structure -- thermogravimetry; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.15329
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: Oxygen desorption/absorption behavior of In‐substituted BaFeO3−δ [BaFe1− x In x O3−δ ] was evaluated using thermogravimetry, high‐temperature X‐ray diffraction, and iodometry. By In substitution of 10% into BaFeO3−δ with ordered distribution of oxide ion vacancy, the structural change to cubic perovskite structure occurred, accompanied by the rearrangement of oxide ion vacancy in random and by the increase in the average valence of Fe ions. The amount of desorbed oxygen per Fe ion was enhanced by only 10% In substitution, which could be attributed to the random distribution of oxide ion vacancies. Among the In‐substituted specimens with almost constant valence of Fe ion, BaFe0.9 In0.1 O3−δ with the highest value of Fe content exhibited the largest amount of desorbed oxygen from the lattice, indicating that this material could be regarded as a promising candidate for oxygen storage materials.