A Self‐Healable, Highly Stretchable, and Solution Processable Conductive Polymer Composite for Ultrasensitive Strain and Pressure Sensing. (15th December 2017)

• Record Type: Journal Article
• Authors: Wang, Tao; Zhang, Ying; Liu, Qingchang; Cheng, Wen; Wang, Xinran; Pan, Lijia; Xu, Baoxing; Xu, Hangxun
• Is Part Of: Advanced functional materials. Volume 28:Number 7(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-12-15
• Subjects: conductive polymers -- flexible electronics -- pressure sensing -- self‐healing polymers -- stretchable electronics; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201705551
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Mimicking human skin's functions to develop electronic skins has inspired tremendous efforts in design and synthesis of novel soft materials with simplified fabrication methods. However, it still remains a great challenge to develop electronically conductive materials that are both stretchable and self‐healable. Here it is demonstrated that a ternary polymer composite comprised of polyaniline, polyacrylic acid, and phytic acid can exhibit high stretchability (≈ 500%) and excellent self‐healing properties. The polymer composite with optimized composition shows an electrical conductivity of 0.12 S cm −1 . On rupture, both electrical and mechanical properties can be restored with≈ 99% efficiency in a 24 h period, which is enabled by the dynamic hydrogen bonding and electrostatic interactions. It is further shown that this composite is both strain and pressure sensitive, and therefore can be used for fabricating strain and pressure sensors to detect a variety of mechanical deformations with ultrahigh sensitivity. The sensitivity and sensing range are the highest among all of the reported self‐healable piezoresistive pressure sensors and even surpass most flexible mechanical sensors. Notably, this composite is prepared via a solution casting process, which potentially allows for large‐area, low‐cost fabrication electronic skins. Abstract : Artificial skin : mimicking human skin's functions to develop skin‐like electronics has inspired tremendous efforts in developing novel soft materials. It is shown that a ternary polymer composite comprised of polyaniline, polyacrylic acid, and phytic acid can exhibit high stretchability (≈500%) and excellent self‐healing properties for electronic skin applications with ultrahigh sensitivity.