Visible light-mediated oxidative C(sp3)–H phosphonylation for α-aminophosphonates under oxidant-free conditions. Issue 13 (29th January 2018)

• Record Type: Journal Article
• Authors: Niu, Linbin; Wang, Shengchun; Liu, Jiamei; Yi, Hong; Liang, Xing-An; Liu, Tianyi; Lei, Aiwen
• Is Part Of: Chemical communications. Volume 54:Issue 13(2018)
• Page Start: 1659
• Page End: 1662
• Publication Date: 2018-01-29
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc09624k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An external oxidant-free synthesis of α-aminophosphonates by synergistically combining photocatalysis and proton-reduction catalysis is developed herein. Abstract : An external oxidant-free synthesis of α-aminophosphonates by synergistically combining photocatalysis and proton-reduction catalysis is developed herein. The gram-scale experiment demonstrates the potential utility of this protocol. This study may have important implications for the functionalization of oxidant-sensitive C(sp 3 )–H bonds.