Self‐Assembly of TbPc2 Single‐Molecule Magnets on Surface through Multiple Hydrogen Bonding. Issue 5 (11th December 2017)

• Record Type: Journal Article
• Authors: Pedrini, Alessandro; Poggini, Lorenzo; Tudisco, Cristina; Torelli, Martina; Giuffrida, Antonino E.; Bertani, Federico; Cimatti, Irene; Otero, Edwige; Ohresser, Philippe; Sainctavit, Philippe; Suman, Michele; Condorelli, Guglielmo G.; Mannini, Matteo; Dalcanale, Enrico
• Is Part Of: Small. Volume 14:Issue 5(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-12-11
• Subjects: multiple hydrogen bonding -- UPy‐NaPy self‐assembly -- SMM -- terbium double deckers; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201702572
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: The complexation between 2‐ureido‐4[1H]‐pyrimidinone (UPy) and 2, 7‐diamido‐1, 8‐naphthyridine (NaPy) is used to promote the mild chemisorption of a UPy‐functionalized terbium(III) double decker system on a silicon surface. The adopted strategy allows the single‐molecule magnet behavior of the system to be maintained unaltered on the surface. Abstract : A strategy based on multiple hydrogen bonding leads to a monolayer of terbium double decker molecules assembled on silicon maintaining unaltered their single molecule magnet behavior.