Strong UV Emission from Colloidal Eu2+‐Doped BaSO4 Nanoparticles: A Material for Enhancing the Photocatalytic Activity of Carbon Dots. Issue 21 (25th July 2017)

• Record Type: Journal Article
• Authors: Hazra, Chanchal; Samanta, Tuhin; Ganguli, Sagar; Mahalingam, Venkataramanan
• Is Part Of: ChemistrySelect. Volume 2:Issue 21(2017)
• Page Start: 5970
• Page End: 5977
• Publication Date: 2017-07-25
• Subjects: Barium sulphate -- Carbon dots -- Energy transfer -- Europium (II) -- Photocatalysis; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201700647
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: In this article, we report a facile microwave‐assisted green synthetic route for the preparation of highly luminescent water dispersible polyacrylic acid‐coated europium (Eu 2+ )‐doped BaSO4 nanoparticles at low temperature for the first time. Polyacrylic acid coating over nanoparticles renders them water dispersible. Upon ultraviolet (UV) (250 nm) excitation, europium‐doped BaSO4 nanoparticles exhibit a strong and broad UV luminescence near at 368 nm. This emission peak is quite strong and has a relative luminescence quantum yield (QY) of 53 %. The high QY of the UV emission from the nanoparticles is explored for the enhancement of the visible photocatalytic properties of the carbon dots (Cdots). In fact, faster degradation of the Rhodamine B is noted for the mixture containing both Eu 2+ ‐doped BaSO4 nanoparticles and cetyl trimethylamonium bromide capped carbon dots. This is attributed to the strong overlap of the UV emission of Eu 2+ with the absorption spectrum of Cdots leading to high energy transfer efficiency (∼64 %). The energy transfer process is supported by the observation of lower dye degradation for the diluted colloidal mixtures where the average distance between Eu 2+ in BaSO4 to Cdots nanoparticles is increased. Abstract : Water dispersible Eu 2+ ‐doped BaSO4 nanoparticles have been prepared for the first time using a microwave method. Upon 250 nm excitation, Eu 2+ ‐doped BaSO4 nanoparticles display strong UV luminescence near 368 nm which is explored for enhancing the visible light photocatalytic activity of carbon dots (CDs) via resonance energy transfer (RET). The RET is supported by the observation of lower dye degradation for the diluted colloidal mixtures where the average distance between Eu 2+ in BaSO4 to Cdots nanoparticles is increased.