Distal radical migration strategy: an emerging synthetic means. (27th November 2017) - Li, Weipeng
Abstract : In the past three years, we have witnessed the rapid development of C–C and C–H bond functionalization by means of long-distance radical migration events which bring us a new platform to deal with the challenging C–C and C–H bond functionalization. Abstract : The remote radical migration strategy has gained considerable momentum. During the past three years, we have witnessed the rapid development of sustainable and practical C–C and C–H bond functionalization by means of long-distance 1, n -radical migration ( n = 4, 5, 6) events. Its advent brings our chemical community a new platform to deal with the challenging migration transformations and thus complements the existing ionic-type migration protocols. In this review, the recent achievements in distal radical migration triggered C–C and C–H bond functionalization are summarized.