Blending Fe3O4 into a Ni/NiO composite for efficient and stable bifunctional electrocatalyst. (20th February 2018)

• Record Type: Journal Article
• Authors: Xie, Yiming; Wang, Xianfu; Tang, Kai; Li, Qun; Yan, Chenglin
• Is Part Of: Electrochimica acta. Volume 264(2018)
• Page Start: 225
• Page End: 232
• Publication Date: 2018-02-20
• Subjects: Synergistic effects -- Nano interface -- Bifunctional electrocatalyst -- Oxygen evolution -- Hydrogen evolution; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2018.01.136
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: As a promising strategy for clean energy production, electrochemical water splitting requires high-efficient, well-stable, and earth-abundant electrocatalysts to realize its practical application. Herein, we report a heterogeneous Fe3 O4 -blended Ni/NiO composite fabricated through a salt-template method as highly active bifunctional catalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). To reach a current density of 10 mA cm −2, the Ni/NiO/Fe3 O4 requires low overpotential of 258 mV for OER in alkaline media and 206 mV for HER in acidic media, respectively, much lower than those of Ni/NiO, Fe3 O4 and other Ni-based oxides. The excellent electrocatalytic performance can be ascribed to the enhanced charge-transfer kinetics between Ni and Fe sites and improved active sites resulted from the large nano-interface between Ni compounds and Fe3 O4 . This work provides a new method to design high-performance non-noble metal Ni-based electrocatalysts by incorporating Fe-doping and nano-interface-fabrication together, which can also be applied to develop other novel hybrid electrocatalysts for practical application.