Three different types of bridging ligands in a 3d–3d′–3d′′ heterotrimetallic chain. Issue 4 (21st December 2017)

• Record Type: Journal Article
• Authors: Alexandru, Maria-Gabriela; Visinescu, Diana; Shova, Sergiu; Andruh, Marius; Lloret, Francesc; Cano, Joan; Julve, Miguel
• Is Part Of: Dalton transactions. Volume 47:Issue 4(2017)
• Page Start: 1010
• Page End: 1013
• Publication Date: 2017-12-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt04586g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A novel example of an antiferromagnetically coupled {Cu II Mn II Cr III } heterotrispin chain with double phenoxido, single cyanido and oxalato as bridging ligands was obtained by a one-pot synthesis. Abstract : A one-pot synthesis of a 3d–3d′–3d′′ heterotrimetallic coordination polymer with double diphenoxido, single cyanido and bis-bidentate oxalate as alternating bridges which exhibits an overall antiferromagnetic behaviour has been developed.