Synthesis of M-UiO-66 (M = Zr, Ce or Hf) employing 2, 5-pyridinedicarboxylic acid as a linker: defect chemistry, framework hydrophilisation and sorption properties. Issue 4 (12th December 2017)

• Record Type: Journal Article
• Authors: Waitschat, S.; Fröhlich, D.; Reinsch, H.; Terraschke, H.; Lomachenko, K. A.; Lamberti, C.; Kummer, H.; Helling, T.; Baumgartner, M.; Henninger, S.; Stock, N.
• Is Part Of: Dalton transactions. Volume 47:Issue 4(2017)
• Page Start: 1062
• Page End: 1070
• Publication Date: 2017-12-12
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt03641h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : MOFs of general composition [M6 (OH)4 (O)4 (PDC)6− x (Cl)2 x (H2 O)2 x ] with M = Zr, Ce, Hf; and 0 ≤ x ≤ 2 were obtained and characterised in detail. Abstract : Metal–organic frameworks of general composition [M6 (OH)4 (O)4 (PDC)6− x (Cl)2 x (H2 O)2 x ] with M = Zr, Ce, Hf; PDC 2− = 2, 5-pyridinedicarboxylate and 0 ≤ x ≤ 2 were obtained under reflux using formic, nitric or acetic acid as an additive. Rietveld refinements carried out using a fixed occupancy of the linker molecules according to the results of thermogravimetric measurements confirmed that the MOFs crystallize in the UiO-66 type structure and demonstrate that the structural models describe the data well. Further characterization was carried out by NMR spectroscopy, thermogravimetric analysis, Zr K-edge EXAFS- and Ce L3 -edge XANES measurements. To highlight the influence of the additional nitrogen atom of the pyridine ring, luminescence and vapour sorption measurements were carried out. The hydrophilisation of the MOFs was shown by the adsorption of water at lower p / p 0 (<0.2) values compared to the corresponding BDC-MOFs (0.3). For water and methanol stability cycling adsorption experiments were carried out to evaluate the MOFs as potential adsorbents in heat transformation applications.