Preparation and Structure Study of Water-Blown Polyurethane/RDX Gun Propellant Foams. Issue 1 (2nd January 2018)

• Record Type: Journal Article
• Authors: Yang, Weitao; Yang, Jianxing; Zhao, Yuhua; Zhang, Yucheng
• Is Part Of: Journal of energetic materials. Volume 36:Issue 1(2018)
• Page Start: 121
• Page End: 126
• Publication Date: 2018-01-02
• Subjects: Foamed propellant -- polyurethane/RDX -- porous structure -- water-blown; Explosives -- Periodicals; Propellants -- Periodicals; 662.2
• DOI: 10.1080/07370652.2017.1320598
• Languages: English
• ISSNs: 0737-0652

Abstract

ABSTRACT: Water-blown polyurethane/RDX foamed propellants were prepared using polyols and isocyanate as reactive binder system, hexogen (RDX) as energetic component, triethanolamine (TEA)/Ditin butyl dilaurate (T-12) as composite catalysts, and H2 O as blowing agent. The influences of catalyst ratio, blowing agent amount, and solid filler content on the inner porous structure were studied. The results show that the balance of gel rate and cream rate that could be adjusted by catalyst ratio is a major influencing factor on porous structure of foamed propellants. When the ratio of TEA/T-12 was adjusted to 1/0.7, the morphology of the foamed propellant exhibited spherical and closed porous structure. Besides, when the water amount was increased from 0.1% to 0.5%, the pore size increased from 0.43 to 0.64 mm. The contents of RDX particles affected the cell nucleation and thus, the cell geometry. When the blowing agent amount was constant, the increased content of RDX filler led to a decreased pore size. The closed bomb test results showed that foamed propellants burned progressively in an in-depth combustion mode.