Kinetic behaviour of a metal-polymer composite suitable for hydrogen storage applications. (1st January 2014)

• Record Type: Journal Article
• Authors: Santecchia, Eleonora; Barucca, Gianni; Majni, Giuseppe; Mengucci, Paolo; Checchetto, Riccardo; Carotenuto, Gianfranco
• Is Part Of: International journal of nanotechnology. Volume 11:Number 9/10/11(2014)
• Page Start: 829
• Page End: 842
• Publication Date: 2014-01-01
• Subjects: hydrogen storage -- metal–polymer composites -- Pd-nanoparticles -- HRSEM -- XRD.; 620.505
• DOI: 10.1504/IJNT.2014.063792
• Languages: English
• ISSNs: 1475-7435

Abstract

Hydrogen storage in composite materials is a feasible way to overcome the main drawbacks of the metal hydride systems. In the present paper, we report on the hydrogenation properties of three polydimethylsiloxane (PDMS)–palladium composite samples with different content of metallic fraction (5, 15, 50 in wt.%). Hydrogenation tests in different conditions of temperature and pressure were performed using a Sievert's type apparatus, while the microstructure of the samples was characterised by means of scanning electron microscopy observations and X-ray diffraction measurements. Results show that the hydrogen storage capacity is inversely proportional to the metallic content in the composite samples.