Structural Insights from 59Co Solid‐State NMR Experiments on Organocobalt(I) Catalysts. Issue 2 (21st December 2017)

• Record Type: Journal Article
• Authors: Burgess, Kevin M. N.; Widdifield, Cory M.; Xu, Yang; Leroy, César; Bryce, David L.
• Is Part Of: Chemphyschem. Volume 19:Issue 2(2018)
• Page Start: 227
• Page End: 236
• Publication Date: 2017-12-21
• Subjects: catalysts -- cobalt -- oxidation state -- quadrupolar coupling -- solid-state NMR; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201700990
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: A series of fumarate‐based organocobalt(I) [CoCp(CO)(fumarate)] catalysts is synthesized and characterized by X‐ray crystallography, multinuclear ( 13 C and 59 Co) solid‐state NMR spectroscopy, and 59 Co NQR spectroscopy. Given the dearth of 59 Co solid‐state NMR studies on Co I compounds, the present work constitutes the first systematic characterization of the 59 Co electric field gradient and chemical shift tensors for a series of cobalt complexes in this oxidation state. Using X‐ray crystallography, the molecular geometry about the Co I centre is found to be nearly identical in all compounds studied herein. Owing to the 59 Co nucleus' large chemical shift range, solid‐state NMR experiments are found to be able to detect small structural differences between the individual organocobalt(I) compounds. With the aid of density functional theory calculations on these complexes, it is shown that the 59 Co chemical shift anisotropy and the 59 Co quadrupolar coupling constant are both extremely sensitive gauges of the Fu‐Co‐Cp bond angle, providing a link between these 59 Co NMR observables and the catalysts' structures. Abstract : Complex chemistry : A series of organocobalt(I) catalysts is synthesized and characterized by X‐ray diffraction, multinuclear ( 13 C and 59 Co) solid‐state NMR spectroscopy, and 59 Co NQR spectroscopy. With the aid of DFT calculations on these complexes, the authors show that the 59 Co chemical shift anisotropy and the 59 Co quadrupolar coupling constant are both extremely sensitive gauges of the structures of these catalysts. This work constitutes the first systematic characterization of the 59 Co electric field gradient and chemical shift tensors for cobalt complexes in the +1 oxidation state.