A highly stable indium based metal organic framework for efficient arsenic removal from water. Issue 3 (18th December 2017)

• Record Type: Journal Article
• Authors: Atallah, Hala; ELcheikh Mahmoud, Mahmoud; Jelle, Abdinoor; Lough, Alan; Hmadeh, Mohamad
• Is Part Of: Dalton transactions. Volume 47:Issue 3(2017)
• Page Start: 799
• Page End: 806
• Publication Date: 2017-12-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt03705h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Indium based metal organic framework crystals (AUBM-1) were successfully synthesized via a solvothermal synthesis process. SXRD analysis showed the production of a new In-MOF structure with apts topology. AUBM-1 was shown to be chemically stable and was used as an adsorbent to efficiently remove arsenic from water. Abstract : A new porous indium metal organic framework namely (AUBM-1) was successfully synthesized via a solvothermal reaction of pyromellitic acid and indium chloride. Single crystal X-ray analysis revealed the formation of a 3D framework with apts topology. The resulting MOF structure showed high chemical stability at different pH values. Thus, the activated indium MOF was applied for As removal from water for the first time and showed a high arsenate uptake capacity of 103.1 mg g −1 at neutral pH, which is higher than the commercial adsorbents (usually less than 100 mg g −1 at neutral pH). Finally, the kinetics and thermodynamic studies revealed that the As adsorption was an endothermic process and followed a pseudo-second-order kinetic model.