A Bifunctional Perovskite Promoter for Polysulfide Regulation toward Stable Lithium–Sulfur Batteries. Issue 2 (27th November 2017)

• Record Type: Journal Article
• Authors: Kong, Long; Chen, Xiang; Li, Bo‐Quan; Peng, Hong‐Jie; Huang, Jia‐Qi; Xie, Jin; Zhang, Qiang
• Is Part Of: Advanced materials. Volume 30:Issue 2(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-11-27
• Subjects: bifunctional perovskite promoters -- composite cathodes -- lithium–sulfur batteries -- polysulfide redox reactions -- shuttle of polysulfide intermediates; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201705219
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Lithium‐sulfur (LiS) batteries are strongly considered as the next‐generation rechargeable cells. However, both the shuttle of lithium polysulfides (LiPSs) and sluggish kinetics in random deposition of lithium sulfides (Li2 S) significantly degrade the capacity, rate performance, and cycling life of LiS cells. Herein, bifunctional Ba0.5 Sr0.5 Co0.8 Fe0.2 O3− δ perovskite nanoparticles (PrNPs) are proposed as a promoter to immobilize LiPSs and guide the deposition of Li2 S in a LiS cell. The oxygen vacancy in PrNPs increases the metal reactivity to anchor LiPSs, and co‐existence of lithiophilic (O) and sulfiphilic (Sr) sites in PrNP favor the dual‐bonding (LiO and SrS bonds) to anchor LiPSs. The high catalytic nature of PrNP facilitates the kinetics of LiPS redox reaction. The PrNP with intrinsic LiPS affinity serves as nucleation sites for Li2 S deposition and guides its uniform propagation. Therefore, the bifunctional LiPS promoter in LiS cell yields high rate performance and ultralow capacity decay rate of 0.062% (a quarter of pristine LiS cells). The proposed strategy to immobilize LiPSs, promotes the conversion of LiPS, and regulates deposition of Li2 S by an emerging perovskite promoter and is also expected to be applied in other energy conversion and storage devices based on multi‐electron redox reactions. Abstract : A bifunctional Ba0.5 Sr0.5 Co0.8 Fe0.2 O3 − δ perovskite is proposed as a promoter to immobilize lithium polysulfides (LiPSs) and guide Li2 S deposition in a working Li–S battery. The coexistence of lithiophilic and sulfiphilic sites in perovskites favors dual bonding (LiO and SrS bonds) to anchor LiPSs. The Li–S cells with perovskite promoters yield high rate performance and ultralow capacity decay rate.