Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids. Issue 12 (21st November 2017)

• Record Type: Journal Article
• Authors: Zhou, Fengling; Azofra, Luis Miguel; Ali, Muataz; Kar, Mega; Simonov, Alexandr N.; McDonnell-Worth, Ciaran; Sun, Chenghua; Zhang, Xinyi; MacFarlane, Douglas R.
• Is Part Of: Energy & environmental science. Volume 10:Issue 12(2017)
• Page Start: 2516
• Page End: 2520
• Publication Date: 2017-11-21
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c7ee02716h
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : High faradaic efficiency reduction of N2 to NH3 is achieved in ionic liquid media under ambient conditions. Abstract : Ammonia as the source of most fertilizers has become one of the most important chemicals globally. It also is being increasingly considered as an easily transported carrier of hydrogen energy that can be generated from "stranded" renewable-energy resources. However, the traditional Haber–Bosch process for the production of ammonia from atmospheric nitrogen and fossil fuels is a high temperature and pressure process that is energy intensive, currently producing more than 1.6% of global CO2 emissions. An ambient temperature, electrochemical synthesis of ammonia is an attractive alternative approach, but has, to date, not been achieved at high efficiency. We report in this work the use of ionic liquids that have high N2 solubility as electrolytes to achieve high conversion efficiency of 60% for N2 electro-reduction to ammonia on a nanostructured iron catalyst under ambient conditions.