Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1, 3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1, 4‐Rhodium(I) Migration. Issue 51 (24th November 2017) - Callingham, Michael
Abstract: A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1, 3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1, 4‐rhodium(I) migration. Abstract : A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1, 3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1, 4‐rhodium(I) migration. t Am= tert ‐amyl.