Effect of Air‐Aging on the Electrochemical Characteristics of TiOxCy Films for Electrocatalysis Applications. Issue 12 (19th October 2017)

• Record Type: Journal Article
• Authors: Rüdiger, Celine; Valero‐Vidal, Carlos; Favaro, Marco; Agnoli, Stefano; Granozzi, Gaetano; Kunze‐Liebhäuser, Julia
• Is Part Of: ChemElectroChem. Volume 4:Issue 12(2017)
• Page Start: 3100
• Page End: 3109
• Publication Date: 2017-10-19
• Subjects: charge transfer -- electrochemical impedance spectroscopy -- solid/liquid interface -- surface chemistry -- titanium oxycarbide; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.201700912
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: We report on the electrochemical characteristics of pristine and air‐aged carbon‐modified titania electrodes in acidic electrolyte, which find applications as catalyst supports in electrocatalysis. Films with different chemical compositions (including TiO2, TiO x, TiO, TiC, C) are synthesized through a carbothermal treatment of compact anodic TiO2 on Ti substrates at different temperatures, and are analyzed with X‐ray photoelectron spectroscopy. Their activity towards heterogeneous outer‐sphere electron transfer and their stability against passivation and corrosion under anodic polarization are investigated by means of electrochemical impedance spectroscopy. It is found that a high fraction of TiC in the pristine carburized films in combination with a thin TiO2 surface layer yields high electron‐transfer kinetics even after aging for 9 months, and a high corrosion and passivation resistance until approximately 0.74VSHE . This finding is essential to the material's application as a catalyst support in general. Abstract : Coming of age : TiO x C y electrodes undergo surface oxidation to TiO2 during air exposure, which has an important impact on their interfacial conductivity and corrosion kinetics in acidic electrolyte.