Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1, 3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1, 4‐Rhodium(I) Migration. (24th November 2017)

Record Type:: Journal Article
Title:: Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1, 3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1, 4‐Rhodium(I) Migration. (24th November 2017)
Main Title:: Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1, 3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1, 4‐Rhodium(I) Migration
Authors:: Callingham, Michael
Partridge, Benjamin M.
Lewis, William
Lam, Hon Wai
Abstract:: Abstract: A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1, 3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1, 4‐rhodium(I) migration.
Is Part Of:: Angewandte Chemie. Volume 129:Number 51(2017)
Journal:: Angewandte Chemie
Issue:: Volume 129:Number 51(2017)
Issue Display:: Volume 129, Issue 51 (2017)
Year:: 2017
Volume:: 129
Issue:: 51
Issue Sort Value:: 2017-0129-0051-0000
Page Start:: 16570
Page End:: 16574
Publication Date:: 2017-11-24
Subjects:: Allylierungen -- Asymmetrische Katalyse -- Imine -- Isomerisierungen -- Rhodium
Chemistry -- Periodicals
540
Journal URLs:: http://onlinelibrary.wiley.com/ ↗
DOI:: 10.1002/ange.201709334 ↗
Languages:: English
ISSNs:: 0044-8249
Deposit Type:: Legaldeposit
View Content:: Available online (eLD content is only available in our Reading Rooms) ↗
Physical Locations:: British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store
Ingest File:: 5539.xml