Addition of azomethine ylides to carbon-encapsulated iron nanoparticles. Issue 1 (6th December 2017)

• Record Type: Journal Article
• Authors: Kasprzak, Artur; Nowicka, Anna M.; Sek, Jakub P.; Fronczak, Maciej; Bystrzejewski, Michał; Koszytkowska-Stawinska, Mariola; Poplawska, Magdalena
• Is Part Of: Dalton transactions. Volume 47:Issue 1(2017)
• Page Start: 30
• Page End: 34
• Publication Date: 2017-12-06
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt03689b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Carbon-encapsulated iron nanoparticles have been covalently functionalized using the Prato reaction. Abstract : The Prato reaction was applied for the covalent introduction of a variety of organic moieties onto carbon-encapsulated iron nanoparticles. The developed method is versatile and employs a broad range of commercially available reactants, including both aromatic and aliphatic aldehydes. The reported functionalization route provides high functionalization yields ( ca. 12–21 wt%).