Raman antenna effect from exciton–phonon coupling in organic semiconducting nanobelts. Issue 48 (4th December 2017)

• Record Type: Journal Article
• Authors: Wang, Mao; Gong, Yi; Alzina, Francesc; Svoboda, Ondrej; Ballesteros, Belén; Sotomayor Torres, Clivia M.; Xiao, Senbo; Zhang, Zhiliang; He, Jianying
• Is Part Of: Nanoscale. Volume 9:Issue 48(2017)
• Page Start: 19328
• Page End: 19336
• Publication Date: 2017-12-04
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c7nr07212k
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : Raman antenna effect resulting from the coupling of molecular excitons and intramolecular phonons are reported in organic semiconducting nanobelts of 6, 13-dichloropentacene (DCP). Abstract : The highly anisotropic interactions in organic semiconductors together with the soft character of organic materials lead to strong coupling between nuclear vibrations and exciton dynamics, which potentially results in anomalous electrical, optical and optoelectrical properties. Here, we report on the Raman antenna effect from organic semiconducting nanobelts 6, 13-dichloropentacene (DCP), resulting from the coupling of molecular excitons and intramolecular phonons. The highly ordered crystalline structure in DCP nanobelts enables the precise polarization-resolved spectroscopic measurement. The angle-dependent Raman spectroscopy under resonant excitation shows that all Raman modes from the skeletal vibrations of DCP molecule act like a nearly perfect dipole antenna I Raman ∝ cos 4 ( θ − 90), with almost zero (maximum) Raman scattering parallel (perpendicular) to the nanobelt's long-axis. The Raman antenna effect in DCP nanobelt is originated from the coupling between molecular skeletal vibrations and intramolecular exciton and the confinement of intermolecular excitons. It dramatically enhances the Raman polarization ratio ( ρ = I ‖ / I ⊥ > 25) and amplifies the anisotropy of the angle-dependent Raman scattering ( κ Raman = I max / I min > 12) of DCP nanobelts. These findings have crucial implications for fundamental understanding on the exciton–phonon coupling and its effects on the optical properties of organic semiconductors.