Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework. Issue 47 (1st November 2017)

• Record Type: Journal Article
• Authors: Depauw, Hannes; Nevjestić, Irena; Wang, Guangbo; Leus, Karen; Callens, Freddy; De Canck, Els; De Buysser, Klaartje; Vrielinck, Henk; Van Der Voort, Pascal
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 47(2017)
• Page Start: 24580
• Page End: 24584
• Publication Date: 2017-11-01
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7ta08103k
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Abstract : A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.