Old meets new: Combination of PLA and RDRP to obtain sophisticated macromolecular architectures. (January 2018)

• Record Type: Journal Article
• Authors: Yildirim, Ilknur; Weber, Christine; Schubert, Ulrich S.
• Is Part Of: Progress in polymer science. Volume 76(2018)
• Page Start: 111
• Page End: 150
• Publication Date: 2018-01
• Subjects: AGET activator generated by electron transfer -- AlpGP 1, 2:3, 4-Di-O-isopropylidene-6-O-acryloyl-α-d-galactopyranose -- ATRP atom-transfer radical polymerization -- BEMP 2-tert-butylimino-2-diethylamino-1, 3-dimethylperhydro-1, 3, 2-diazaphosphorine -- BGMA cis-1, 3-benzylidene glycerol methacrylate -- BIEMA 2-bromoisobutyryl methacrylate -- BMBIBPC 2, 2-Bis(methylene-2-bromoisobutyrate) propionyl chloride -- BnA benzyl acrylate -- Bpy bipyridine -- BS 4-(3-butenyl)styrene -- CEMA 2-chloroethyl methacrylate -- CLM 2-cholinium lactate methacrylate -- CTA chain transfer agent -- CuAAC copper catalyzed 1, 3 dipolar azide alkyne cycloaddition -- Đ dispersity -- DAEMA dehydroabietic ethyl methacrylate -- DBU 1, 8-diazabicyclo[5.4.0]undec-7-ene -- DCC N, N′-dicyclohexylcarbodiimide -- DG degree of grafting -- DMA N, N-dimethylacrylamide -- DMAc N, N-dimethylacetamide -- DMAEA 2-(dimethylamino)ethyl acrylate -- DMAEMA 2-(dimethylamino)ethyl methacrylate -- DMAP 4-(N, N-dimethylamino)pyridine -- DOX doxorubicin -- DP degree of polymerization -- DTM dithiomaleimide -- DTT dithiothreitol -- DVB p-divinylbenzene -- EA ethyl acrylate -- EtOxnMA oligo(2-ethyl-2-oxazoline) methacrylate -- FMA pentafluorophenyl methacrylate -- FRP free radical polymerization -- GAMA d-gluconamidoethyl methacrylate -- GlyMA glycerol monomethacrylate -- GMA glycidyl methacrylate -- HEA 2-hydroxyethyl acrylate -- HEMA 2-hydroxyethyl methacrylate -- HMTETA 1, 1, 4, 7, 10, 10-hexamethyltriethylenetetramine -- Imes 1, 3-dimesitylimidazol-2-ylidene -- MA methyl acrylate -- Me6TREN Tris[2-(dimethylamino)ethyl]amine -- MM macromonomer -- MMA methyl methacrylate -- MPC 2-(methacryloyloxy ethyl phosphonylcholine) -- MPEO poly(ethylene oxide) methyl ether -- MWCNT multi-walled carbon nanotube -- NAS N-acryloxysuccinimide -- NB p-norbornenylethyl styrene -- nBA n-butyl acrylate -- NiPAm N-iso-propylacrylamide -- NMP nitroxide-mediated polymerization -- NMR nuclear magnetic resonance -- NVP N-vinylpyrrolidone -- P(rac-LA) Poly(racemic lactide) -- P2-t-Bu 1-tert-butyl-2, 2, 4, 4, 4-pentakis(dimethylamino)-2Λ5, 4Λ5-catenadi-(phosphazene) -- PAA poly(acrylic acid) -- PAGP poly(6-O-acryloyl-α-d-galactopyranose) -- PAN polyacrylonitrile -- PBnA poly(benzyl acrylate) -- PCL poly(ε-caprolactone) -- PDLA poly(d-lactide) -- PDLLA poly(d, l-lactide) -- PDMA poly(N, N-dimethylacrylamide) -- PDMAEA poly(2-(dimethylamino)ethyl acrylate) -- PDMAEMA poly(2-(dimethylamino)ethyl methacrylate) -- PDMS poly(dimethylsiloxane) -- PEO poly(ethylene oxide) -- PEOnA poly(ethylene oxide) acrylate -- PEOnMA poly(ethylene oxide) methacrylate -- PEOnMAGlc glucopyranoside grafted poly(ethylene oxide) methacrylate -- PFMA pentafluorophenyl methacrylate -- PFS poly(4-fluorostyrene) -- PGMA poly(glycidyl methacrylate) -- PHEA poly(2-hydroxyethyl acrylate) -- PHEMA poly(2-hydroxyethyl methacrylate) -- PLA polylactide -- PLAnMA polylactide methacrylate -- PLGA poly(lactide-co-glycolide) -- PLLA poly(l-lactide) -- PMA poly(methyl acrylate) -- PMAA poly(methacrylic acid) -- PMDETA N, N, N′, N′′, N′′-pentamethyldiethylenetriamine -- PMMA poly(methyl methacrylate) -- PMPC poly(2-(methacryloyloxy ethyl phosphonylcholine)) -- PNiPAm poly(N-iso-propylacrylamide) -- PNVCL poly(N-vinylcaprolactam) -- PNVP poly(N-vinylpyrrolidone) -- PS polystyrene -- PtBA poly(tert-butyl acrylate) -- PtBMA poly(tert-butyl methacrylate) -- PtBuS poly(tert-butyl styrene) -- PTHPA poly(tetrahydropyran acrylate) -- rac-LA racemic lactide -- RAFT reversible addition-fragmentation chain transfer -- RAPTA-C dichlororuthenium(II)(p-cymene)(1, 3, 5-triaza-7-phosphaadamantane) -- RDRP reversible-deactivation radical polymerization -- ROMP ring-opening metathesis polymerization -- ROP ring-opening polymerization -- S styrene -- SEC size exclusion chromatography -- SG-1 N-tert-butyl-N-[1-diethoxyphosphoryl-2, 2-dimethylpropyl] nitroxide -- SiPMA 5-(trimethylsilyl)-4-pentyn-1-ol methacrylate -- SKA solketal acrylate -- SKMA solketal methacrylate -- SMA stearyl methacrylate -- Sn(Oct)2 tin(II) octoate -- tBA tert-butyl acrylate -- tBMA tert-butyl methacrylate -- tBuS tert-butyl styrene -- TEMPO 2, 2, 6, 6-tetramethyl-1-piperidinyloxyl -- THF tetrahydrofuran -- TIPNO 2, 2, 5-trimethyl-4-phenyl-3-azahexane-3-oxyl -- VBzCl 4-vinylbenzyl chloride; ROP -- Lactide -- RDRP -- ATRP -- RAFT -- NMP; Polymers -- Periodicals; Polymerization -- Periodicals; Polymers -- Industrial applications -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.progpolymsci.2017.07.010
• Languages: English
• ISSNs: 0079-6700

Abstract

Abstract: This review article highlights the research focused on the synthesis of polylactide (PLA) based copolymers by combination of reversible-deactivation radical polymerization (RDRP) techniques with ring-opening polymerization (ROP) processes. In particular atom-transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization, and nitroxide-mediated polymerization (NMP) will be addressed as RDRP techniques mechanistically different from ROP in the design of various sophisticated macromolecular structures. The combination of ROP with RDRP techniques has been extensively applied to prepare PLA copolymers. We discuss the synthetic methods applicable to prepare linear and star-shaped block copolymers by use of heterofunctional initiators as well as other end functionalization methods. This is complemented with the adaption of the synthetic pathways generally used for the preparation of comb and graft copolymers, i.e., macromonomer, grafting-from and grafting-onto approaches, to the requirements of PLA-based building blocks.