Synthesis of hybrid materials using graft copolymerization on non-cellulosic polysaccharides via homogenous ATRP. (January 2018)

• Record Type: Journal Article
• Authors: Seidi, Farzad; Salimi, Hamid; Shamsabadi, Ahmad Arabi; Shabanian, Meisam
• Is Part Of: Progress in polymer science. Volume 76(2018)
• Page Start: 1
• Page End: 39
• Publication Date: 2018-01
• Subjects: AAP 4-aminoantipyrine -- AGET activators generated by electron transfer -- AGP agarose palmitate -- AGU anhydroglucose unit -- AMIMB 1-allyl-3-methylimidazolium bromide -- AS acetylated starch -- Au NPs gold nanoparticles -- BIBA α-bromoisobutyric acid -- BIBB 2-bromo-isobutyryl bromide -- bipy 2, 2-bipyridine -- BPL β-propionolactone -- BSA bovine serum albumin -- CBMA carboxybetaine methacrylate -- CDI 1, 1′-carbonyldiimidazole -- CPCl 2-chloropropionyl chloride -- CS chitosan -- CSO water-soluble chitosan oligomers -- Đ dispersity -- DE-ATRP deactivation enhanced atom transfer radical polymerization -- DEA diethylamine -- DEGCholA diethylene glycol cholesteryl ether acrylate -- DEGMA di(ethylene glycol) methyl ether methacrylate -- Dex dextrane -- DexAcBr acetyl protected dextran macroinitiator -- DexBr unprotected dextran macroinitiators -- DMAc N, N-dimethylacetamide -- DMAP N, N-dimethylaminopyridine -- DS degree of substitution -- Dxt dextrin -- EA ethanolamine -- EDC 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride -- EtHex ethyl hexanoate -- GAG glycosaminoglycan -- GGBr guar gum macroinitiator -- Gly glycogen -- HA hyaluronic acid (Hyaluronan) -- HEMA 2-hydroxyethyl methacrylate -- HM hydrophobically modification -- HMTETA 1, 1, 4, 7, 10, 10-hexamethyltriethylenetetramine -- HOBt hydroxybenzotriazole -- LAMA lactobionamidoethyl methacrylate -- LBG locust bean gum -- LCST lowest critical solution temperature -- MANa sodium methacrylate -- Me6TREN tris(2-dimethylaminoethyl)amine -- MMA methyl methacrylate -- n-Pr-PMI N-(n-propyl)-2-pyridylmethanimine -- NBPS N-(2-bromo-2-methylpropionyloxy) succinimide -- NHS N-hydroxysuccinimide -- NIPAAm N-isopropylacrylamide -- PAA poly(acrylic acid) -- PCL poly(ε-caprolactone) -- PDEAEMA poly(2-(N, N-diethylamino)ethyl methacrylate) -- PDEGCholA poly(diethylene glycol cholesteryl ether acrylate) -- PDEGMA poly(di(ethylene glycol) methyl ether methacrylate) -- PDMAEMA poly(2-(N, N-dimethylamino)ethyl methacrylate) -- PDMAPS poly[3-dimethyl(methacryloyloxyethyl) ammonium propanesulfonate] -- PEO poly(ethylene oxide) -- PGMA poly(glycidyl methacrylate) -- PhCS-g-(PDEAEMA-b-PEO) N-phthaloylchitosan-graft-poly(2-(N, N-diethylamino)ethyl methacrylate)-block-poly(ethylene oxide) -- PhCS-g-PDMAEMA N-phthaloylchitosan-graft-poly[2-(N, N-dimethylamino) ethyl methacrylate] -- PHEMA poly(2-hydroxyethyl methacrylate) -- PLAMA poly(lactobionamidoethyl methacrylate) -- PMDETA N, N, N′, N″, N‴-pentamethyldiethylenetriamine -- PMMA poly(methyl methacrylate) -- PNIPAAm poly(N-isopropylacrylamide) -- POEGMA poly(oligo(ethylene glycol)methacrylate) -- PS polystyrene -- Pull pullulan -- PuPGEA biocleavable pullulan-based gene vector -- PVAc poly(vinyl acetate) -- Py pyridine -- QDPD quaternized PDMAEMA-graft-dextran -- QPDMAEMA quaternized poly[2-(dimethylamino)ethyl methacrylate] -- RBCs rabbit red blood cells -- ROP ring-opening polymerization -- SBMA sulfobetaine methacrylate -- SCC SDS–chitosan complex -- SDS sodium dodecylsulfate -- SPMA 3-sulfopropyl methacrylate potassium salt -- SS-Pullulan-Br bromoisobutylryl-terminated pullulan -- SS-Pullulan-NH2 disulfide bond-containing pullulan -- TBA tetrabutylammonium salt -- TCS CS(-g-PDMAEMA)-g-PNIPAAm terpolymers -- TEOS tetraethyl orthosilicate -- TMC trimethylated chitosan -- UCST upper critical solution temperature -- UFH unfractionated heparin; ATRP -- Polysaccharides -- Homogeneous -- Grafting -- Chitosan -- Pullulan -- Dextran -- Agarose -- Hyaluronic acid -- Hyaluronan -- Starch -- Amylose -- Amylopectin -- Glycogen -- Heparin -- Chitin -- Guar gum -- Locust bean gum -- Dextrin; Polymers -- Periodicals; Polymerization -- Periodicals; Polymers -- Industrial applications -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.progpolymsci.2017.07.006
• Languages: English
• ISSNs: 0079-6700

Abstract

Abstract: Inclusion of various polymeric chains with different lengths and functionalities (such as hydrophobic, ionic, acidic, basic, etc) into polysaccharide backbones leads to new polymeric materials with interesting properties that may self-assembled into different aggregations and have the potential to for use in a variety of applications. This review highlights the application of various ATRP techniques (such as "grafting-from" and "grafting-to") to modify non-cellulosic polysaccharides under homogenous condition. Chemical modification of chitosan, pullulan, dextran, agarose, hyaluronic acid (hyaluronan), starch, glycogen, heparin, chitin, guar gum, locust bean gum, and dextrin using ATRP are described. Pre-functionalization or protection of some functional groups in the polysaccharide backbone required in some cases to prepare a precursor with higher solubility in organic solvents is illustrated. For each polymerization, the strategy for synthesis of the copolymer and the condition of the polymerization is described in detail along with the properties of the prepared copolymers. Furthermore, examples that produced materials with the potential for use in a specific application are reviewed in summary.