Brønsted acidity in deep eutectic solvents and ionic liquids. (19th September 2017)

• Record Type: Journal Article
• Authors: Abbott, Andrew P.; Alabdullah, Sahar S. M.; Al-Murshedi, Azhar Y. M.; Ryder, Karl S.
• Is Part Of: Faraday discussions. Volume 206(2018)
• Page Start: 365
• Page End: 377
• Publication Date: 2017-09-19
• Subjects: Chemistry -- Periodicals; Metallurgy -- Periodicals; Electrochemistry -- Periodicals; 540
• DOI: 10.1039/c7fd00153c
• Languages: English
• ISSNs: 1359-6640

Abstract

Abstract : Relative pH values are calculated using an indicator dye and a glass electrode, and they are found to provide consistent results. Abstract : Despite the importance of ionic liquids in a variety of fields, little is understood about the behaviour of protons in these media. The main difficulty arises due to the unknown activity of protons in non-aqueous solvents. This study presents acid dissociation constants for nine organic acids in deep eutectic solvents (DESs) using standard pH indicator solutes. The p K In value for bromophenol blue was found by titrating the DES with triflic acid. The experimental method was developed to understand the acid–base properties of deep eutectic solvents, and through this study it was found that the organic acids studied were slightly less dissociated in the DES than in water with p K a values between 0.2 and 0.5 higher. p K In values were also determined for two ionic liquids, [Bmim][BF4 ] and [Emim][acetate]. The anion of the ionic liquid changes the pH of the solution by acting as a buffer. [Emim][acetate] was found to be more basic than water. It is also shown that water significantly affects the pH of ionic liquids. This is thought to arise because aqueous mixtures with ionic liquids form heterogeneous solutions and the proton partitions into the aqueous phase. This study also attempted to develop an electrochemical pH sensor. It was shown that a linear response of cell potential vs. ln a H + could be obtained but the slope for the correlation was less than that obtained in aqueous solutions. Finally it was shown that the liquid junction potential between two reference electrodes immersed in different DESs was dependent upon the pH difference between the liquids.