Manipulating and quantifying spin states in solution as a function of pressure and temperature. Issue 2 (8th December 2017)

• Record Type: Journal Article
• Authors: Hogue, Ross W.; Lepper, Christopher P.; Jameson, Geoffrey B.; Brooker, Sally
• Is Part Of: Chemical communications. Volume 54:Issue 2(2018)
• Page Start: 172
• Page End: 175
• Publication Date: 2017-12-08
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc08104a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : This new 'single compartment tube' 1 H NMR methodology for determining spin states under high pressures (up to 240 MPa) has implications for the study of magnetic, catalytic and biochemical processes. Abstract : Monitoring the spin states of species in solution is a crucial aspect of understanding magnetic properties as well as spin-labile sensing, supramolecular, catalytic and biochemical processes. Herein, we describe the first quantitative variable-pressure and variable-temperature method of determining spin states in solution, demonstrate that it is accurate, and identify a simultaneous T and P sensor system.