Chiral amine-catalyzed asymmetric conjugate addition of aldehydes to α-phenylselenoenones as formal Z-allylating agents. Issue 2 (8th December 2017) - Kano, Taichi
Abstract : α-Selenoenones could be employed as Z -allyl precursors in the chiral amine-catalyzed asymmetric conjugate addition of aldehydes. Abstract : α-Selenoenones could be employed as Z -allyl precursors in the chiral amine-catalyzed asymmetric conjugate addition of aldehydes. The obtained formal allylation product, a Z -olefin having a sulfonate leaving group, was employed as a synthetically useful chiral alkylating agent.