Size-dependent optical properties of conjugated polymer nanoparticles. Issue 88 (12th December 2017)

• Record Type: Journal Article
• Authors: Lin, Ye; Dong, Chaoqing; Cao, Fengwen; Xiong, Liqin; Gu, Hongchen; Xu, Hong
• Is Part Of: RSC advances. Volume 7:Issue 88(2017)
• Page Start: 55957
• Page End: 55965
• Publication Date: 2017-12-12
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c7ra12164d
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The systematic understanding of size-dependent optical properties of conjugated polymer nanoparticles is rather significant to the selecting of labelling materials. Abstract : A strong and stable fluorescent signal is the crux for the ultrasensitive biodetection technology, conjugated polymer nanoparticles (CPNs) as new fluorescence labels have attracted more and more attention for their excellent optical properties. However, a systematic understanding of the size-dependent optical properties of CPNs with diameters from the nano to submicron ranges is lacking, which is the most important issue when choosing label materials. Hence, poly[(9, 9-dioctylfluorenyl-2, 7-diyl)- co -(1, 4-benzo-{2, 1′, 3}-thiadiazole)] (PFBT) nanoparticles with sizes from 50 nm to 200 nm were synthesized and studied. It was demonstrated that the spectroscopic and fluorescent properties are similar for CPNs with different sizes. The relationship between single-particle brightness and diameter was investigated via fluorescence spectrometry and fluorescence correlation spectroscopy (FCS), and the results presented that the single-particle brightness increased quadratically with the increase of the diameter of CPNs. This research may provide valuable support to further application of CPNs in biological diagnostics.