Cost-effective fabrication of ZnO/g-C3N4 composite film coated stainless steel meshes for visible light responsive photocatalysis. (March 2018)

• Record Type: Journal Article
• Authors: Ravichandran, K.; Kalpana, K.; Uma, R.; Sindhuja, E.; seelan, K. Shantha
• Is Part Of: Materials research bulletin. Volume 99(2018)
• Page Start: 268
• Page End: 280
• Publication Date: 2018-03
• Subjects: Photocatalysis -- Stainless steel mesh substrate -- ZnO/g-C3N4 composite film -- Tubular nebulizer pyrolysis; Materials -- Periodicals; Crystal growth -- Periodicals; Matériaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Crystal growth; Materials; Periodicals; 620.11
• DOI: 10.1016/j.materresbull.2017.11.010
• Languages: English
• ISSNs: 0025-5408

Abstract

Graphical abstract: Highlights: First report on the photocatalytic efficacy of ZnO/g-C3 N4 composite thin film coated stainless steel mesh. A homemade automated tubular nebulizer spray pyrolysis technique is used to deposit the samples. All supplementary studies (SEM, XPS, FTIR and PL) support the enhancement photocatalytic activity. Abstract: The ZnO and ZnO/g-C3 N4 composite films were deposited on stainless steel meshes having different apertures (370, 500, 780 and 1000 μm) using a simple cost-effective automated tubular nebulizer spray pyrolysis technique for photocatalytic degradation of organic pollutants. Photocatalytic studies were done for the degradation of methylene blue (MB) and malachite green (MG). The photocatalytic studies reveal that the ZnO/g-C3 N4 composite film having smallest aperture exhibits superior photocatalytic activity compared with other meshes. The degradation efficiency of this composite film for MB and MG dyes are 97% (irradiation time-75 min) and 95% (irradiation time-45 min), whereas for pristine ZnO film the corresponding efficiencies are only 88% and 87%. The aperture size related photocatalytic efficiency variations and the effect of g-C3 N4 addition on the photocatalytic efficiency of ZnO films have been addressed with appropriate supporting experimental evidences and reports.