This is an interim version of our Electronic Legal Deposit Catalogue-eJournals and eBooks while we continue to recover from a cyber-attack.
A Full Regioselective and Stereoselective Synthesis of 4‐Nitroisoxazolidines via Stepwise [3 + 2] Cycloaddition Reactions between (Z)‐C‐(9‐Anthryl)‐N‐arylnitrones and (E)‐3, 3, 3‐Trichloro‐1‐nitroprop‐1‐ene: Comprehensive Experimental and Theoretical Study. (8th August 2017)
Record Type:
Journal Article
Title:
A Full Regioselective and Stereoselective Synthesis of 4‐Nitroisoxazolidines via Stepwise [3 + 2] Cycloaddition Reactions between (Z)‐C‐(9‐Anthryl)‐N‐arylnitrones and (E)‐3, 3, 3‐Trichloro‐1‐nitroprop‐1‐ene: Comprehensive Experimental and Theoretical Study. (8th August 2017)
Main Title:
A Full Regioselective and Stereoselective Synthesis of 4‐Nitroisoxazolidines via Stepwise [3 + 2] Cycloaddition Reactions between (Z)‐C‐(9‐Anthryl)‐N‐arylnitrones and (E)‐3, 3, 3‐Trichloro‐1‐nitroprop‐1‐ene: Comprehensive Experimental and Theoretical Study
Abstract : In the contrast to all known [3 + 2] cycloadditions between nitrones and conjugated nitroalkenes, reactions of ( E )‐3, 3, 3‐trichloro‐1‐nitroprop‐1‐ene with ( Z )‐ C ‐(9‐anthryl)‐ N ‐arylnitrones are proceeding in a fully regioselective and stereoselective manner. Additionally, density functional theory calculations suggest stepwise, zwitterionic mechanism of these cycloadditions. Abstract :