Synthesis, crystal structure, and magnetic properties of a novel one-dimensional chain polymer based on 1-(4-nitrophenyl)-1, 2, 4-triazole. Issue 12 (2nd December 2017)

• Record Type: Journal Article
• Authors: Qian, Jin; Wang, Jun; Luo, Qiang; Chen, Ning-Ning; Tao, Jian-Qing
• Is Part Of: Inorganic and nano-metal chemistry. Volume 47:Issue 12(2017)
• Page Start: 1741
• Page End: 1745
• Publication Date: 2017-12-02
• Subjects: coordination polymer -- one-dimensional double chain -- 1-(4-nitrophenyl)-1, 2, 4-triazole -- benzophenone-2, 4′-dicarboxylic acid -- antiferromagnetic interaction; Inorganic compounds -- Synthesis -- Periodicals; Nanostructured materials -- Periodicals; Reactivity (Chemistry) -- Periodicals; Inorganic compounds -- Synthesis; Nanostructured materials; Reactivity (Chemistry); Periodicals; 546
• DOI: 10.1080/24701556.2017.1357626
• Languages: English
• ISSNs: 2470-1556

Abstract

ABSTRACT: A one-dimensional Co(II) complex [Co(BPDC)(NPT)]n (1 ) (H2 BPDC = benzophenone-2, 4′-dicarboxylic acid, NPT = 1-(4-nitrophenyl)-1, 2, 4-triazole) has been synthesized and characterized using single crystal X-ray diffraction, IR and elemental analysis. Single-crystal X-ray diffraction analysis revealed that complex1 is a one-dimensional double chain polymer based on [Co2 (OCO)2 ] binuclear motif. The thermal stability and magnetic properties of complex1 have been investigated, which revealed antiferromagnetic coupling interaction exists between Co(II) ions.